Frederick L. Sayles and William Martin; Woods Hole Oceanographic Institution

"Benthic Cycling and Accumulation of Organic Matter, Biogenic Opal, and CaCO3 in the JGOFS Southern Ocean Study Areas"

We will characterize benthic remineralization, burial, and the role of benthic processes in the cycling of organic matter, CaCO3, and biogenic SiO2 through pore water and sediment studies. Specifically we will 1) Determine the magnitude of fluxes of species central to the recycling of organic matter, CaCO3, and Opal; 2) Define benthic reactions, rates, and the relative importance of various benthic processes in determining variations in them; 3) Identify the factors which influence preservation efficiency and hence control the relation between surface water production and accumulation rate; and 4) Evaluate the relative roles of preservation and sediment focusing in determining the high opal accumulation rates in the PFZ.

MEASUREMENTS: Pore Water: Nutrients, TCO2, Alk, Ca, O2, DOC, *13C, Sediment: uranium series isotopes; SiO2, CaCO3, O, C.; sediment physical properties

INSTRUMENTATION: Wire lowered in situ pore water sampler: collects both pore waters and ~50 cm cores.