Parameterizations for Organic Matter Oxidation Kinetics
William Martin and Frederick Sayles

Southern Ocean: AESOPS transect Data Information
Ceara Rise SMP Project
Cape Verde Plateau
Central Equatorial Pacific
Sierra Leone Rise


Table 1. Southern Ocean: AESOPS transect
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Southern Ocean: AESOPS transect
Station Data Input Data Best-fit Parameters Calculated Fluxes
Site Latitude Longitude Water depth Samples used n data Depth range Colw p0 p1 p2 n j0 j1 j2 j3 Flux (x=0) Pno3 or Co2 Corg ox - R Corg ox - AS
NBP9802-M5 66°08.5S 169°37.5W 3136 NO3 in situ wcs in situ pore water 30 0-50 cm 33 0.7975 0.1278 0.2071 2.4 5.94 2.66 0.048 0.156 2.32 2.32 15.37 16.94
NBP9802-M5/4-1 64°11.8S 170°04.8W 2740-2752 NO3 iswcs ispw lwcs sec/cent > 0.34 cm 36 0-8 cm 32.3 0.9032 0.0655 0.6488 2.41 7.32 1.17 0   5.92 5.92 39.22 43.22
NBP9802-M5/4-2 64°11.8S 170°04.8W 2740-2752 NO3 is wcs 20 0-3.7 cm 32.3 0.9032 0.0655 0.6488 2.41 4.169 0.79 0   4.701 4.70 31.14 34.32
NBP9802-M5/4-3 64°11.8S 170°04.8W 2740-2752 NO3 l wcs 18 0-3.49 33.4 0.9032 0.0655 0.6488 2.41 10.437 1.446 0   6.804 6.80 45.08 49.67
NBP9802-M5/4-4 64°11.8S 170°04.8W 2740-2752 O2 l wcs 18 0-3.39 cm 219 0.9032 0.0655 0.6488 2.41 71.172 1.617 0   57.375 57.38 44.07 39.57
NBP9802-M4 63°10.0S 169°44.5W 2860 NO3 is pw sec / cent 31 0-60 33.7 0.9032 0.0655 0.6488 2.41 5.28 1.31 0.0079 0.047 3.93 3.93 26.04 28.69
NBP9802-M4/3 61°52.5S 169°58.3W 3294-3312 NO3 sec/cent > 0.34 cm 18 0-15 32.3 0.914 0.0622 1.1096 3.24 6.25 1.067 0   5.53 5.53 36.64 40.37
NBP9802-M3-1 60°14.6S 170°11.1W 3900-4032 NO3 is wcs is pw sec/cent > 2 cm 47 0-60 32.6 0.8808 0.0457 0.7493 2.93 0.3009 0.4476 0.0238 0.09088 0.8346 0.83 5.53 6.09
NBP9802-M3-2 60°14.6S 170°11.1W 3900-4032 NO3 lwcs (2 profiles) 37 0-4.96 34.2 0.8808 0.0457 0.7493 2.93 6.154 2.7383 0   2.4851 2.49 16.46 18.14
NBP9802-M3-3 60°14.6S 170°11.1W 3900-4032 O2 lwcs 19 0-4.86 210 0.8808 0.0457 0.7493 2.93 23.855 1.9735 0.4024 1.4984 14.886 14.89 11.43 10.27
NBP9802-M3/2 58°41.3S 169°58.7W 4345 NO3 is wcs sec/cent > 2cm 27 0-15 32.7 0.8778 0.6927 0.381 2.58 1.48 1.14 0.0183 0.0001 1.51 1.51 10.00 11.02
NBP9802-M2 56°53.0S 170°10.3W 4970 NO3 is wcs sec/cent > 2cm 29 0-13.7 32.5 0.8137 0.1242 0.1034 2.2 0.0572 0.088 0   0.422 0.42 2.80 3.08



Table 2. Ceara Rise
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Ceara Rise
Station Data Input Data Best-fit Parameters Calculated Fluxes
Site Latitude Longitude Water depth Samples used n data Depth range Colw p0 p1 p2 n j0 j1 j2 j3 Flux (x=0) Pno3 or Co2 Corg ox - R Corg ox - AS
Kn142-2 B-1 5°16N 44°09W 3279 NO3 lwcs: avg. of 3 sec/cent avg of 3 >= 1.2 cm ispw avg of 4; omit 2, 4 cm 38 0-58 20.8 0.7419 0.1638 1.3918 2.13 5.702 3.197 0.1829 0.2955 1.95 2.00 13.28 14.24
Kn142-2 B-2 5°16N 44°09W 3279 O2 Hales, 1995; Hales & Emerson,1997 avg. of 5 in situ mep 27 0-6.5 253.8 0.7419 0.1638 1.3918 2.13 24.202 2.61 3.751 0.442 15.86 15.86 12.18 10.92
Kn142-2-E 5°27N 44°01W 3772 NO3 lwcs - (0.61,0.77, 0.93 cm) sec/cent >= 1.55 cm ispw; omit 2, 3, 10 cm 29 0-32 21 0.7351 0.153 1.0373 2.53 8.6651 3.5 0.1366 0.2554 2.46 2.52 16.70 17.96
Kn142-2-A-1 5°17N 43°34W 3990 NO3 iswcs sec/cent - 2 cores, >=1.92 & >=2.32 cm ispw > 10 cm 37 0-57 20.9 0.7123 0.1557 0.5117 1.06 0.5711 0.4016 0   1.05 1.11 7.35 7.67
Kn142-2-A-2 5°17N 43°34W 3990 NO3 lwcs sec/cent - 2 cores, >=1.92 & >=2.32 cm ispw > 10 cm 40 0-57 20.9 0.7123 0.1557 0.5117 1.06 3.4486 3 0.4126 0.3608 1.80 1.86 12.32 13.14
Kn142-2-A-3 5°17N 43°34W 3990 O2 Hales, 1995;Hales & Emerson, 1997 1 in situ mep 35 0-7.5 258 0.7123 0.1557 0.5117 1.06 29.9 1.644 0.8914 0.0185 22.23 22.23 17.08 15.30
Kn142-2-F 5°33N 43°36W 4164 NO3 lwcs sec/cent >2.32cm ispw 38 0-34 20.9 0.7123 0.1557 0.5117 1.06 3.6424 3 0.2434 0.2757 1.62 1.70 11.26 11.83
Kn142-2-H 5°46N 43°38W 4267 NO3 is wcs sec/cent >= 3.48 cm ispw 30 0-50 20.75 0.7123 0.1557 0.5117 1.06 0.5416 0.4617 0.1079 0.3063 1.12 1.19 7.90 8.18
Kn142-2-J 5°45N 43°24W 4342 NO3 lwcs sec/cent >= 1.93 ispw; omit 4, 6 cm 34 0-35 21.8 0.7123 0.1557 0.5117 1.06 8.1837 3.5 0.1773 0.2093 2.56 2.62 17.36 18.69
KN142-2-G-1 6°10N 42°53W 4675 NO3 lwcs: avg of 2 sec/cent>2.32cm, avg of 2 ispw: avg of 2; omit 2, 5 cm 33 0-38 27.7 0.7367 0.1667 0.264 1.752 2.1792 3 0.1912 0.241 1.17 1.30 8.58 8.54
KN142-2-G-2 6°10N 42°53W 4675 O2 Hales, 1995; Hales & Emerson,1997 Avg of 4 in situ mep 29 0-7 231.6 0.7367 0.1667 0.264 1.752 3.733 0.5848 0.2314 -0.0435 9.63 9.27 7.12 6.38



Table 3. Cape Verde Plateau
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Cape Verde Plateau
Station Data Input Data Best-fit Parameters Calculated Fluxes
Site Latitude Longitude Water depth Samples used n data Depth range Colw p0 p1 p2 n j0 j1 j2 j3 Flux (x=0) Pno3 or Co2 Corg ox - R Corg ox - AS
Kn159-7-M-1 18°27.8N 21°01.5N 3102 lwcs #1 O2 21 0 - 4.79 cm x* = 6.21 cm 238 0.6972 0.1394 0.6282 2.32 146.715 2.8023 2.9785 0.0937 52.12 52.12 40.03 35.87
Kn159-7-M-2 18°27.8N 21°01.5N 3102 lwcs #2 O2 20 0-4.25 x* = 8.90 238 0.6972 0.1394 0.6282 2.32 52.436 1.396 3.408 0.3212 37.22 37.22 28.59 25.62
Kn159-7-M-3 18°27.8N 21°01.5N 3102 NO3: iswcs ispw:#1 & #2, with #2 heavily edited; the 2 averaged at >=20cm sec > 4 cm 40 0 - 60 cm; note x* = 6.2 for fits 23.3 0.6972 0.1394 0.6282 2.32 14.19 5.18 0.244 0.001 3.027; Fdn=0.440 3.467 22.97 25.31
Kn159-7-M-4 18°27.8N 21°01.5N 3102 NO3: lwcs #1 sec-#1 (all) ispw, #1-(3,4.3, 4.7, 6.1, 11, 11.3, 15.5) ispw, #2-(3, 4.3, 4.7, 6.1, 6.5, 12.9, 15.5) 49 0 - 60 cm; note x* = 6.2 for fits 23.3 0.6972 0.1394 0.6282 2.32 16.781 2.915 0.1778 0.001 5.079; Fdn = 0.400 5.479 36.30 40.00
Kn159-7-L 17°23.4N 21°05.8W 3377 lwcs O2 22 0 - 4.52 cm 210.3 * based on int lwcs O2 0.6509 0.1676 0.2471 1.32 60.419 1.31 1.518 0.01 42.98 42.98 33.01 29.58
Kn159-7-J - 1 14°26.1N 21°54.2W 4243 NO3: iswcs ispw: omit 3, 4.3, 6.1, 6.5,12.9 sec >= 2.336 31 0 - 60 cm 24.8 0.7382 0.1575 0.8975 2 4.1168 2.3251 0.208 0.1453 2.042 Fdn = 0.112 2.154 14.27 15.72
Kn159-7-J - 2 14°26.1N 21°54.2W 4243 NO3: lwcs same ispw sec >=0.701 41 0 - 60 cm 24.8 0.7382 0.1575 0.8975 2 4.612 1.254 0.3623 0.9829 3.213 Fdn = 0.105 3.32 22.00 24.24
Kn159-7-I - 1 12°55.2N 23°21.3W 4762 NO3: iswcs ispw - (4.7, 6.5, 7.6, 11) sec >= 3.503 28 0-20 cm x* = 10 cm 24.44 0.7294 0.1311 0.5428 2.39 1.9742 1.9844 0.1236 0.07986 1.414 Fdn = 0.061 1.475 9.77 10.77
Kn159-7-I - 2 12°55.2N 23°21.3W 4762 NO3: lwcs sec >= 1.16 ispw - (3, 4.7, 6.5, 7.6, 11) 46 0 - 60 cm 24.44 0.7294 0.1311 0.5428 2.39 3.725 1.837 0.1303 0.1323 2.197 Fdn = 0.040 2.237 14.82 16.33
Kn159-7-I - 3 12°55.2N 23°21.3W 4762 lwcs O2 20 0 - 4.255 cm 235.1 0.7294 0.1311 0.5428 2.39 129.2 3.407 0   36.864 36.864 28.32 25.37
Kn159-7-I - 4 12°55.2N 23°21.3W 4762 lwcs NO3 19 0 - 4.096 cm 24 0.7294 0.1311 0.5428 2.39 4.803 2.077 0.00144 2.9738 2.346 2.346 15.54 17.13



Table 4. Central Equatorial Pacific
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Central Equatorial Pacific
Station Data Input Data Best-fit Parameters Calculated Fluxes
Site Latitude Longitude Water depth Samples used n data Depth range Colw p0 p1 p2 n j0 j1 j2 j3 Flux (x=0) Pno3 or Co2 Corg ox - R Corg ox - AS
W8803-T23 134°58W 6°00S 4590 NO3 lwcs 23 0-4.2 35.4 0.8255 0.1333 1.7498 1.7 5.93 2.405 0   2.31 2.31 15.31 16.87
W8803-T31-1 134°58W 2°58S 4570 O2 lwcs 10 0-5.82 182 0.8255 0.1333 1.7498 1.7 151.64 6.116 0.9461 0.01 30.12 30.12 23.13 20.77
W8803-T31-2 134°58W 2°58S 4570 NO3 lwcs 30 0-5.71 33.8 0.8255 0.1333 1.7498 1.7 3.819 2.398 0.1045 0.01 2.15 2.15 14.23 15.68
W8803-T36-1 132°57W 1°59S 4440 NO3 lwcs 17 0-3.4 35.4 0.8327 0.122 2.813 1.7 8.804 2.338 0   3.68 3.68 24.37 26.86
W8803-T36-2 132°57W 1°59S 4440 O2 lwcs 7 0-2.25 166 0.8327 0.122 2.813 1.7 193.08 3.909 0   49.06 49.06 37.69 33.84
W8803-T42-1 133°41W 1°00S 4230 NO3 lwcs 22 0-4.28 35 0.8327 0.122 2.813 1.7 3.547 1.121 0.0129 0.0009 2.88 2.88 19.09 21.04
W8803-T42-2 133°41W 1°00S 4230 O2 lwcs 9 0-4.28 161 0.8327 0.122 2.813 1.7 42.931 1.383 0   28.77 28.77 22.10 19.84
W8803-T47-1 133°19W 0°31N 4330 NO3 lwcs 23 0-3.86 38.5 0.8327 0.122 2.813 1.7 14.506 2.747 0   5.04 5.04 33.39 36.79
W8803-T47-2 133°19W 0°31N 4330 O2 lwcs 9 0-3.86 151 0.8327 0.122 2.813 1.7 67.756 1.629 0   39.69 39.69 30.49 27.37
W8803-T62-1 133°20W 4°14N 4550 NO3 lwcs 22 0-4.0 36.3 0.8327 0.122 2.813 1.7 11.718 3.269 0   3.45 3.45 22.88 25.21
W8803-T62-2 133°20W 4°14N 4550 O2 lwcs 9 0-3.88 170 0.8327 0.122 2.813 1.7 97.262 3.193 0   29.36 29.36 22.55 20.25
W8803-T68 135°04W 5°50N 4535 NO3 lwcs 17 0-3.33 36.7 0.8255 0.1333 1.7498 1.7 7.584 2.434 0   3.09 3.09 20.48 22.56
W8803-T74-1 137°47W 9°03N 4765 NO3 lwcs 21 0-3.49 35.8 0.9307 0.0227 1.3363 1.7 3.545 4.021 0   1.10 1.10 7.25 7.99
W8803-T74-2 137°47W 9°03N 4765 O2 lwcs 8 0-3.08 171 0.9307 0.0227 1.3363 1.7 100.28 4.812 0   22.03 22.03 16.92 15.19
W8803-T89-1 136°31W 10°00N 4850 NO3 lwcs 17 0-2.31 36.8 0.9307 0.0227 1.3363 1.7 0.8382 0.5552 0   1.22 1.22 8.10 8.93
W8803-T89-2 136°31W 10°00N 4850 O2 lwcs 7 0-2.51 166 0.9307 0.0227 1.3363 1.7 9.955 0.9037 0   10.25 10.25 7.87 7.07
W8803-T92-1 136°25W 11°05N 5051 NO3 lwcs 20 0-3.19 36.4 0.9307 0.0227 1.3363 1.7 21.149 5.44 0   3.97 3.97 26.27 28.94
W8803-T92-2 136°25W 11°05N 5051 O2 lwcs 8 0-3.19 168 0.9307 0.0227 1.3363 1.7 118.1 4.051 0   29.39 29.39 22.58 20.27



Table 5. Sierra Leone Rise
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Sierra Leone Rise
Station data Input data Best-fit parameters Calculated fluxes
Site Latitude Longitude Water depth Samples used n data Depth range Colw p0 p1 p2 n j0 j1 j2 j3 Flux (x=0) Pno3 Corg ox - R Corg ox - AS
KN159-7-C 5°31.9N 21°48.4W 3592 iswcs - deepest 2 sec start from 1.2 cm ispw-(4.7, 7.6, 11, 12.9, 30, 60) 37 0-50 cm 23 0.7072 0.1017 0.6321 1.69 0.7223 0.4695 0.0774 0.6493 1.2034 1.242 8.23 9.08
KN159-7-D-1 5°44.7N 22°29.2W 4011 iswcs ispw - 3 very high values sec > 3.5 cm 40 0-50 cm 23.8 0.6979 0.0959 0.4031 2.3 0.3482 0.3434 0   0.729 0.753 4.99 5.51
KN159-7-D-2 5°44.7N 22°29.2W 4011 lwcs sec > 1.16 cm 42 0-17.782 23.8 0.6979 0.0959 0.4031 2.3 0.1647 1.4188 0.4854 0.3891 0.981 1.018 6.74 7.44
KN159-7-D-3 5°44.7N 22°29.2W 4011 lwcs iswcs sec > 1.4 cm ispw-(6.1, 6.5, 7.6, 11, none > 17.8) 61 0-17.8 23.8 0.6979 0.0959 0.4031 2.3 0.3096 0.3045 0   0.7119 0.749 4.96 5.48
KN159-7-E - 1 7°00.2N 24°37.1W 4210 iswcs ispw - 4 low values; only <= 30 cm 16 0 - 30 cm 22.53 0.735 0.0974 0.662 1.68 1.063 0.8377 0.0931 0.2536 1.299 1.299 8.61 9.50
KN159-7-E - 2 7°00.2N 24°37.1W 4210 lwcs ispw - 4 low values; only <= 30 cm 25 0 - 30 cm 23.3 0.735 0.0974 0.662 1.68 2.7128 1.2241 0.08117 0.2954 1.998 1.998 13.24 14.61
KN159-7-F - 1 7°50.4N 24°36.8W 4750 iswcs ispw - (6.1, 6.5, 12.5, 15.5, 50) 19 0 - 60 cm 24.04 0.7453 0.1099 1.336 1.93 0.3054 0.3262 0   0.718 0.718 4.76 5.25
KN159-7-F - 2 7°50.4N 24°36.8W 4750 lwcs sec > 2 cm ispw - (6.1, 6.5, 12.5, 15.5, 50) 43 0 - 60 cm 24.04 0.7453 0.1099 1.336 1.93 0.5527 0.4217 0   1.0114 1.0114 6.70 7.40
KN159-7-G - 1 8°58.6N 24°29.4W 4930 lwcs ispw - (4.7, 15.5, 40) 28 0 - 60 cm 23.2 0.7462 0.1447 1.014 1.36 10.41 3.535 0.1318 0.1993 3.0376 3.0376 20.12 22.21
KN159-7-G - 2 8°58.6N 24°29.4W 4930 lwcs - (0.62, 0.80, 0.967, 1.119, 1.287) ispw - (4.7, 15.5, 40) 23 0 - 60 cm 23.2 0.7462 0.1447 1.014 1.36 9.964 4.228 0.1713 0.2209 2.632 2.632 17.44 19.25
KN159-7-H 10°04.0N 23°12.0W 5120 lwcs sec > 2 cm ispw #1 all +#2 - (40, 50, 60) 61 0 - 60 cm 23.4 0.7717 0.1219 0.7043 1.04 7.8795 3.463 0.3264 0.2763 2.894 2.934 19.44 21.45