Methodology:
1. Ammonium - nanomolar ammonium concentrations, as measured by a
spectrophotometric procedure based on the Berthelot reaction followed
by an extraction step to concentrate the indophenol.
References:
a) Brzezinski, M.A. (1987) Colorimetric
Determination of nanomolar concentrations of
ammonium in seawater using solvent extraction.
Marine Chemistry, 20, 277-288.
b) Selmer, J.S. and F. Sorensson (1986) New
Procedure for extraction of ammonium from natural
waters for 15N isotopic ratio determinations.
Applied Environmental Microbiology, 52, 577-579.
2. Urea - urea concentration as measured by a spectrophotometric
procedure based on the diacetylmonoxime reaction.
Reference:
Whitledge, T.E., S.C. Malloy, et al. (1981)
Automated nutrient analysis in seawater. Department
of Energy and Environment, Brookhaven National
Laboratory, Upton, NY.
3. N-15 uptake -
A. Uptake rates for nitrate and urea were measured by incubation
experiments to follow the incorporation of trace additions of N-15
labeled substrate into particulate material collected by Whatman GF/F
filters.
Reference:
Sambrotto,R.N., J.H. Martin, et al. (1993) Nitrate
utilization in surface waters of the Iceland Basin
during spring and summer of 1989. Deep-Sea Research II.
Vol. 40, No.1/2, 441-457.
B. Methodology for ammonium rates was similar to that for
nitrate and urea, except that modified isotope dilution model was used
to calculate uptake.
Reference:
Glibert, P. M., F. Lipschultz, et al. (1982).
Isotope dilution models of uptake and remineralization
of ammonium by phytoplankton. Limnology and
Oceanography 27: 639-650.
4. Particulate carbon and nitrogen - the concentration of either
particulate carbon or nitrogen as measured by collection on Whatman
GF/F filters, followed by Dumas combustion, cryogenic separation and
manometric analysis.